2015 Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
* Average orientation of water in CH2F2⋯H2O from the (17)O quadrupole effects in the rotational spectrum of CH2F2⋯H2(17)O.
- The rotational spectrum of the CH2F2⋯H2(17)O adduct has been measured in the 6.5-18.5 GHz range using a pulsed jet Fourier-transform microwave spectrometer. The experimental values of the (17)O quadrupole coupling constants have been determined to be χaa=-3.853(6), χbb=-3.259(1) and χcc=7.112(9) MHz, respectively. These data correspond to an average value of the angle between the water plane and the FCF plane of about 23°.
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